@article { author = {Ranjbar, Maryam and Yousefi, Mostafa and Shahsavan, Nasrin and Yousefi, Mohammad and Jalilian, Ehsan and Eriksson, Lars}, title = {Sonochemical synthesis and characterization of nano-sized zinc(II) coordination complex as a precursor for the preparation of pure-phase zinc(II) oxide nanoparticles}, journal = {Nanochemistry Research}, volume = {2}, number = {1}, pages = {120-131}, year = {2017}, publisher = {Iranian Chemical Society}, issn = {2538-4279}, eissn = {2423-818X}, doi = {10.22036/ncr.2017.01.011}, abstract = {In current study, nanoparticles and single crystals of a Zn(II) coordination complex, [Zn(dmph)I2](1), {dmph=2,9-dimethyl-1,10-phenanthroline(neocuproine)}, have been synthesized by the reaction of zinc(II) acetate, KI and neocuproine as ligand in methanol using sonochemical and heat gradient methods, respectively. The nanostructure of 1 was characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRD), FT-IR spectroscopy and elemental analyses, and the structure of compound 1 was determined by single-crystal X-ray diffraction. The thermal stability of nano-sized 1 has been studied by thermogravimetric (TG) and differential thermal analyses (DTA). Structural determination of compound 1 reveals the Zn(II) ion is four-coordinated in a distorted tetrahedral configuration by two N atoms from a 2,9-dimethyl-1,10-Phenanthroline ligand and two terminal I atoms. The effect of supercritical condition on stability, size and morphology of nano-structured compound 1 has also been studied. The XRD pattern of the residue obtained from thermal decomposition of nano-sized compound 1 at 600 °C under air atmosphere provided pure phase of ZnO with the average particles size of about 31 nm.}, keywords = {crystal structure,Neocuproine,Sonochemical method,Thermal analyses,Zinc oxide nanoparticles}, url = {http://www.nanochemres.org/article_49503.html}, eprint = {http://www.nanochemres.org/article_49503_ea8c57ea10f9378480d99b87d1ee9bd6.pdf} }