ORIGINAL_ARTICLE
Effective fabrication of poly(anilin-formaldehyde)-supported hybrid nanomaterial and catalytic synthesis of dihydropyridines
In this study, Fe3O4@SiO2-PAF-SO3H nanocomposite was successfully fabricated by immobilization of sulfonic acid groups on the surface of poly(anilin-formaldehyde)-supported on magnetic Fe3O4@SiO2 nanoparticles through layer-by-layer assembly. Fe3O4@SiO2-PAF-SO3H composite nanostructure has been fully characterized using various techniques including the Fourier-transform infrared spectroscopy (FT-IR), X-ray powder diffraction patterns (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and vibrating sample magnetometry (VSM). The one-pot synthesis of mono and bis 1,4-dihydropyridine derivatives, as pharmaceutically interesting compounds, have been achieved in high yields via three-component and pseudo five component condensation of an aromatic aldehyde, ammonium acetate and ethyl acetoacetate in the presence of Fe3O4@SiO2-PAF-SO3H as a novel retrievable hybrid nanocatalyst under solvent-free conditions. This protocol has advantages in terms of short reaction time, solvent-free condition, high yield and purity, easy work-up and eco-friendly process as well as recyclability of the nanocatalyst (at least 6 times) with no decrease in catalytic activity.
http://www.nanochemres.org/article_104933_a0ae50f6528b3c26e31209dfcac81851.pdf
2019-10-01
101
111
10.22036/ncr.2019.02.001
Surface modification
Magnetic nanoparticle
Multi-component reactions
1
4-Dihydropyridine
Mohammad Ali
Bodaghifard
mbodaghi2007@yahoo.com
1
Department of Chemistry, Faculty of Science, Arak University, Iran
LEAD_AUTHOR
Zahra
Faraki
z.faraki89@gmail.com
2
Department of Chemistry, Faculty of Science, Arak University, Iran
AUTHOR
Sajad
Asadbegi
sajad.asadbegi@gmail.com
3
Department of Chemistry, Faculty of Science, Arak University, Iran
AUTHOR
1. Polshettiwar V, Luque R, Fihri A, Zhu H, Bouhrara M, Basset J-M. Magnetically Recoverable Nanocatalysts. Chemical Reviews. 2011;111(5):3036-75.
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2. Shylesh S, Schünemann V, Thiel WR. Magnetically Separable Nanocatalysts: Bridges between Homogeneous and Heterogeneous Catalysis. Angewandte Chemie International Edition. 2010;49(20):3428-59.
2
3. Bodaghifard MA, Hamidinasab M, Ahadi N. Recent Advances in the Preparation and Application of Organic– inorganic Hybrid Magnetic Nanocatalysts on Multicomponent Reactions. Current Organic Chemistry. 2018;22(3):234-67.
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4. Sau TK, Rogach AL, Jäckel F, Klar TA, Feldmann J. Properties and Applications of Colloidal Nonspherical Noble Metal Nanoparticles. Advanced Materials. 2010;22(16):1805-25.
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5. Wu D-Y, Liu X-M, Huang Y-F, Ren B, Xu X, Tian Z-Q. Surface Catalytic Coupling Reaction of p-Mercaptoaniline Linking to Silver Nanostructures Responsible for Abnormal SERS Enhancement: A DFT Study. The Journal of Physical Chemistry C. 2009;113(42):18212-22.
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6. Minakata S, Komatsu M. Organic Reactions on Silica in Water. Chemical Reviews. 2009;109(2):711-24.
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7. Kitanosono T, Masuda K, Xu P, Kobayashi S. Catalytic Organic Reactions in Water toward Sustainable Society. Chemical Reviews. 2017;118(2):679-746.
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8. Narayanan R, El-Sayed MA. Catalysis with Transition Metal Nanoparticles in Colloidal Solution: Nanoparticle Shape Dependence and Stability. The Journal of Physical Chemistry B. 2005;109(26):12663-76.
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9. Jiménez-Alonso S, Chávez H, Estévez-Braun A, Ravelo ÁG, Feresin G, Tapia A. An efficient synthesis of embelin derivatives through domino Knoevenagel hetero Diels–Alder reactions under microwave irradiation. Tetrahedron. 2008;64(37):8938-42.
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10. Dömling A. Isocyanide based multi component reactions in combinatorial chemistry. Comb Chem High Throughput Screen. 1998;1(1):1-22.
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11. Dömling A, Ugi I. Multicomponent Reactions with Isocyanides. Angewandte Chemie. 2000;39(18):3168-210.
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12. Nair V, Rajesh C, Vinod AU, Bindu S, Sreekanth AR, Mathen JS, et al. Strategies for Heterocyclic Construction via Novel Multicomponent Reactions Based on Isocyanides and Nucleophilic Carbenes. Accounts of Chemical Research. 2003;36(12):899-907.
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13. Bajaj SD, Mahodaya OA, Tekade PV. ZSM-5 Catalyzed Solvent Free Ecofriendly Synthesis of Substituted Pyrimidine Derivatives. Pharmaceutical Chemistry Journal. 2015;48(10):679-82.
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14. Schnell B, Strauss UT, Verdino P, Faber K, Kappe CO. Synthesis of enantiomerically pure 4-aryl-3,4-dihydropyrimidin-2(1 H )-ones via enzymatic resolution: preparation of the antihypertensive agent ( R )-SQ 32926 †Synthesis and reactions of Biginelli compounds, part 20; for part 19, see: Kappe, C. O.; Shishkin, O. V.; Uray, G.; Verdino, P. Tetrahedron 2000, 56, 1859–1862. †. Tetrahedron: Asymmetry. 2000;11(7):1449-53.
14
15. Gaudio AC, Korolkovas A, Takahata Y. Quantitative Structure-Activity Relationships for 1,4-Dihydropyridine Calcium Channel Antagonists (Nifedipine Analogues): A Quantum ChemicalKlassical Approach. Journal of Pharmaceutical Sciences. 1994;83(8):1110-5.
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16. Schleifer K-J. Stereoselective Characterization of the 1,4-Dihydropyridine Binding Site at L-Type Calcium Channels in the Resting State and the Opened/Inactivated State. Journal of Medicinal Chemistry. 1999;42(12):2204-11.
16
17. Khadilkar B, Borkar S. Silica Gel Supported Ferric Nitrate: A Convenient Oxidizing Reagent. Synthetic Communications. 1998;28(2):207-12.
17
18. Schnell B, Krenn W, Faber K, Kappe CO. Synthesis and reactions of Biginelli-compounds. Part 23. Chemoenzymatic syntheses of enanttiomerically pure 4-aryl-3,4-dihydropyrimidin-2(1H)-ones. Journal of the Chemical Society, Perkin Transactions 1. 2000(24):4382-9.
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19. Janis RA, Triggle DJ. New developments in calcium ion channel antagonists. Journal of Medicinal Chemistry. 1983;26(6):775-85.
19
20. Boecker RH, Guengerich FP. Oxidation of 4-aryl- and 4-alkyl-substituted 2,6-dimethyl-3,5-bis(alkoxycarbonyl)-1,4-dihydropyridines by human liver microsomes and immunochemical evidence for the involvement of a form of cytochrome P-450. Journal of Medicinal Chemistry. 1986;29(9):1596-603.
20
21. Gordeev MF, Patel DV, Gordon EM. Approaches to Combinatorial Synthesis of Heterocycles: A Solid-Phase Synthesis of 1,4-Dihydropyridines. The Journal of Organic Chemistry. 1996;61(3):924-8.
21
22. Pattan SR, Rasal VP, Venkatramana NV, Khade AB, Butle SR, Jadhav SG, et al. Synthesis and Evaluation of Some 1,4-Dihydropyridine and Their Derivatives as Antihypertensive Agents. ChemInform. 2007;38(32).
22
23. Suresh T, Swamy SK, Reddy VM. Synthesis and Bronchodilatory Activity of New 4-Aryl-3,5-bis (2-chlorophenyl)carbamoyl-2,6-dimethyl-1,4-dihydropyridines and Their 1-Substituted Analogues. ChemInform. 2007;38(22).
23
24. Chen F, Xie S, Zhang J, Liu R. Synthesis of spherical Fe3O4 magnetic nanoparticles by co-precipitation in choline chloride/urea deep eutectic solvent. Materials Letters. 2013;112:177-9.
24
25. Morel A-L, Nikitenko SI, Gionnet K, Wattiaux A, Lai-Kee-Him J, Labrugere C, et al. Sonochemical Approach to the Synthesis of Fe3O4@SiO2 Core−Shell Nanoparticles with Tunable Properties. ACS Nano. 2008;2(5):847-56.
25
26. Moghanian H, Mobinikhaledi A, Blackman AG, Sarough-Farahani E. Sulfanilic acid-functionalized silica-coated magnetite nanoparticles as an efficient, reusable and magnetically separable catalyst for the solvent-free synthesis of 1-amido- and 1-aminoalkyl-2-naphthols. RSC Adv. 2014;4(54):28176-85.
26
27. Petcharoen K, Sirivat A. Synthesis and characterization of magnetite nanoparticles via the chemical co-precipitation method. Materials Science and Engineering: B. 2012;177(5):421-7.
27
28. Tamaddon F, Ghazi S. Urease: A highly biocompatible catalyst for switchable Biginelli reaction and synthesis of 1,4-dihydropyridines from the in situ formed ammonia. Catalysis Communications. 2015;72:63-7.
28
29. Sharma P, Gupta M. Silica functionalized sulphonic acid coated with ionic liquid: an efficient and recyclable heterogeneous catalyst for the one-pot synthesis of 1,4-dihydropyridines under solvent-free conditions. Green Chemistry. 2015;17(2):1100-6.
29
30. Tamaddon F, Razmi Z, Jafari AA. Synthesis of 3,4-dihydropyrimidin-2(1H)-ones and 1,4-dihydropyridines using ammonium carbonate in water. Tetrahedron Letters. 2010;51(8):1187-9.
30
ORIGINAL_ARTICLE
Luminescence and scintillation characterization of Silver doped KCl single crystal grown by Czochralski technique for photonic applications
In this study, the scintillation and optical properties of pure and silver doped potassium chloride (KCl:Ag) single crystals were reported. Pure and doped KCl bulk single crystals with a good optical quality and free from cracks were grown from the melt using Czochralski technique. Different analysis methods were used to study the optical and scintillation properties of the grown crystals. The XRD, EDX and SEM results confirmed the formation of KCl compound. The UV excitation, X and gamma rays were employed to evaluate the scintillation and optical properties of the synthesized samples. The X-ray induced luminescence spectrum of doped crystal showed the prominent blue emission at 400-460 nm wavelength region. Also, the thermoluminescence response of doped sample showed a strong TL glow peak at 200 and proper linear ranges as a function of dose making it a promising candidate for dosimetry and photonic applications.
http://www.nanochemres.org/article_98904_ba4ff90ab20d6719349b42dd98ab2d5c.pdf
2019-10-01
112
118
10.22036/ncr.2019.02.002
Czochralski technique
KCl
Doping
Luminescence Properties
Sanaz
Alamdari
alamdarisanaz@gmail.com
1
Semnan University, Semnan, Iran
AUTHOR
Mohammad
Hemmati
alamdarisanz@gmail.com
2
Faculty of Physics, Semnan University, Semnan, Iran
AUTHOR
Majid
Jafar tafreshi
tafr@gmail.com
3
Faculty of Physics, Semnan University, Semnan, Iran
LEAD_AUTHOR
Morteza
Sasani ghamsari
msasi@gmail.com
4
Photonics and Quantum Technologies Research School, Nuclear Science and Technology Research Institute, Tehran, Iran
AUTHOR
Hosein
Afarideh
afaridehm@gmail.com
5
Department of Energy Engineering and Physics, Amirkabir University of Technology, Tehran, Iran
LEAD_AUTHOR
Aghil
Mohammadi
amohammadi@gmail.com
6
Department of Energy Engineering and Physics, Amirkabir University of Technology, Tehran, Iran
AUTHOR
Yoon sang
Kim
y.skimk@gmail.com
7
Department of Computer Science and Engineering, Korea University of Technology and Education, Cheonan, South Korea
AUTHOR
Mohammad Hosein
Majles Ara
8
Applied Science Research Center(ASRC), Kharazmi University, Tehran, Iran
AUTHOR
1. Dickens PT, Haven DT, Friedrich S, Lynn KG. Scintillation properties and increased vacancy formation in cerium and calcium co-doped yttrium aluminum garnet. Journal of Crystal Growth. 2019;507:16-22.
1
2. Krishnakumar DN, Rajesh NP. Luminescence characteristics of silver and rare earth co-doped KCl single crystals grown from melt using Czochralski technique. Optik. 2019;183:148-53.
2
3. Samavat F, Ali EH, Solgi S, Ahmad PT. KCl single crystals growth with Mn, Ag and in impurities by Czochralski method and study of impurities influence on their properties. Open Journal of Physical Chemistry. 2012;2(03):185.
3
4. Singh S, Tyagi M, Desai D, Singh A, Tiwari B, Sen S, et al. Development of technologically important crystals and devices. In the Forthcoming issue. 2011 (318).
4
5. Galenin E, Sidletskiy O, Dujardin C, Gektin A. Growth and Characterization of SrI2:Eu Crystals Fabricated by the Czochralski Method. IEEE Transactions on Nuclear Science. 2018;65(8):2174-7.
5
6. Kara S, Bouhdjer L, Sebais M, Halimi O, Boudine B. Original research article. Optik-International Journal for Light and Electron Optics. 2016; 127(20): 9264-8.
6
7. Bouhdjer L, Addala S, Chala A, Halimi O, Boudine B, Sebais M. Elaboration and characterization of a KCl single crystal doped with nanocrystals of a Sb2O3semiconductor. Journal of Semiconductors. 2013;34(4):043001.
7
8. Polosan S, Tsuboi T, Apostol E, Topa V. Electrolytic reduction of Tl+ ions in KCl crystals. Optical Materials. 2007;30(1):95-7.
8
9. Kumar S, Sinha N, Bhukkal S, Kumar B. Growth of pure and BFO doped KCl crystals by Czochralski technique and fabrication of microstrip patch antenna for GHz applications. Journal of Materials Science: Materials in Electronics. 2019;30(3):2118-26.
9
10. Kara S, Bouhdjer L, Sebais M, Halimi O, Boudine B. Elaboration and characterization of a KCl single crystal doped with Er3+. Optik. 2016;127(20):9264-8.
10
11. Shiehpour M, Solgi S, Tafreshi MJ, Ghamsari MS. ZnO-doped KCl single crystal with enhanced UV emission lines. Applied Physics A. 2019;125(8):531.
11
12. Das H, Podder J. Growth, structural, optical and microhardness study of KCl doped triglycine sulphate (TGS) crystals for photonic applications. Journal of Optoelectronics and Advanced Materials. 2013; 15(7-8): 1142-6.
12
13. Mishra K, Giri NK, Rai SB. Preparation and characterization of upconversion luminescent Tm3+/Yb3+ co-doped Y2O3 nanophosphor. Applied Physics B. 2011;103(4):863-75.
13
14. Kawai T, Hirai T. Luminescence properties of KCl:Ag− crystals excited near the fundamental absorption edge. Journal of Luminescence. 2012;132(2):513-6.
14
15. Ranfagni A, Mugnai D, Bacci M, Viliani G, Fontana MP. The optical properties of thallium-like impurities in alkali-halide crystals. Advances in Physics. 1983;32(6):823-905.
15
16. Jacobs PWM. Alkali halide crystals containing impurity ions with the ns2 ground-state electronic configuration†. Journal of Physics and Chemistry of Solids. 1991;52(1):35-67.
16
ORIGINAL_ARTICLE
The Stage Dependent Effect of Capping Agent Introduction in the Synthesis of Magnetite Nanoparticles
In this paper, three techniques to obtain capped magnetite nanoparticles were compared. In the formation of magnetite nanoparticles via the co-precipitation route, capping agents were introduced pre-, simultaneously with, or post-addition of the precipitating agent, ammonia. The amino acids L-glutamine and L-glutamic acid were used as the capping agents. Characterization via TEM, pXRD, EDX, and magnetic analysis displayed that the stage of introduction affected the properties of the nanoparticles obtained. Confirmation of capping was performed by FTIR and X-ray photoelectron spectroscopy. TEM displayed that the post-addition method yielded nanoparticles with the narrowest size distributions, having attractive dispersity values. The pre- and simultaneously-introduced methods produced smaller nanoparticles but had relatively higher size distributions. Crystallite size determined from pXRD showed that the post-addition method had the highest crystallite size, even compared to the uncapped nanoparticles, while the pre-introduced were much less crystalline. From the magnetic studies, the post-introduction method was shown to yield the highest magnetic saturation values, even when taking magnetically dead layers into account. It was also shown that the simultaneous and pre-introduction methods yielded similar magnetic saturation values despite size differences.
http://www.nanochemres.org/article_97034_4b44b7db2bc919872ac850201cb31e3e.pdf
2019-10-01
119
131
10.22036/ncr.2019.02.003
Magnetite nanoparticles
Amino acids
Capping agent
Matthew
Hickson
m.v.hickson@gmail.com
1
Department of Chemistry, Nelson Mandela University, Port Elizabeth, 6031, South Africa
LEAD_AUTHOR
Zenixole
Tshentu
zenixole.tshentu@mandela.ac.za
2
Department of Chemistry, Nelson Mandela University, Port Elizabeth, 6031, South Africa
AUTHOR
Richard
Betz
richard.betz@mandela.ac.za
3
Department of Chemistry, Nelson Mandela University, Port Elizabeth, 6031, South Africa
AUTHOR
[1] Mahmoudi M, Sant S, Wang B, Laurent S, Sen T. Superparamagnetic iron oxide nanoparticles (SPIONs): Development, surface modification and applications in chemotherapy. Advanced Drug Delivery Reviews. 2011;63(1-2):24-46.
1
[2] Gnanaprakash G, Mahadevan S, Jayakumar T, Kalyanasundaram P, Philip J, Raj B. Effect of initial pH and temperature of iron salt solutions on formation of magnetite nanoparticles. Materials Chemistry and Physics. 2007;103(1):168-75.
2
[3] Laurent S, Forge D, Port M, Roch A, Robic C, Vander Elst L, et al. ChemInform Abstract: Magnetic Iron Oxide Nanoparticles: Synthesis, Stabilization, Vectorization, Physicochemical Characterizations, and Biological Applications. ChemInform. 2008;39(35).
3
[4] Gupta AK, Gupta M. Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications. Biomaterials. 2005;26(18):3995-4021.
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[5] Babes L, Denizot Bt, Tanguy G, Le Jeune JJ, Jallet P. Synthesis of Iron Oxide Nanoparticles Used as MRI Contrast Agents: A Parametric Study. Journal of Colloid and Interface Science. 1999;212(2):474-82.
5
[6] Kim DK, Zhang Y, Voit W, Rao KV, Muhammed M. Synthesis and characterization of surfactant-coated superparamagnetic monodispersed iron oxide nanoparticles. Journal of Magnetism and Magnetic Materials. 2001;225(1-2):30-6.
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[7] Alp E, Aydogan N. A comparative study: Synthesis of superparamagnetic iron oxide nanoparticles in air and N 2 atmosphere. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2016;510:205-12.
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[8] Fang M, Ström V, Olsson RT, Belova L, Rao KV. Particle size and magnetic properties dependence on growth temperature for rapid mixed co-precipitated magnetite nanoparticles. Nanotechnology. 2012;23(14):145601.
8
[9] Park JY, Patel D, Choi ES, Baek MJ, Chang Y, Kim TJ, et al. Salt effects on the physical properties of magnetite nanoparticles synthesized at different NaCl concentrations. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2010;367(1-3):41-6.
9
[10] Mahdavi M, Ahmad M, Haron M, Namvar F, Nadi B, Rahman M, et al. Synthesis, Surface Modification and Characterisation of Biocompatible Magnetic Iron Oxide Nanoparticles for Biomedical Applications. Molecules. 2013;18(7):7533-48.
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[12] Wolf EL. Nanophysics and Nanotechnology: John Wiley and Sons; 2008.
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[13] Wang Z, Zhu H, Wang X, Yang F, Yang X. One-pot green synthesis of biocompatible arginine-stabilized magnetic nanoparticles. Nanotechnology. 2009;20(46):465606.
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[14] Si S, Li C, Wang X, Yu D, Peng Q, Li Y. Magnetic Monodisperse Fe3O4Nanoparticles. Crystal Growth & Design. 2005;5(2):391-3.
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[15] Baumgartner E, Blesa MA, Marinovich HA, Maroto AJG. ChemInform Abstract: Heterogeneous electron transfer as a pathway in the dissolution of magnetite in oxalic acid solutions. Chemischer Informationsdienst. 1983;14(45).
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[16] Nematollahzadeh A, Abdekhodaie MJ, Shojaei A. Submicron nanoporous polyacrylamide beads with tunable size for verapamil imprinting. Journal of Applied Polymer Science. 2011;125(1):189-99.
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[17] Iyengar SJ, Joy M, Maity T, Chakraborty J, Kotnala RK, Ghosh S. Colloidal properties of water dispersible magnetite nanoparticles by photon correlation spectroscopy. RSC Advances. 2016;6(17):14393-402.
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[18] Sun S, Zeng H. Size-Controlled Synthesis of Magnetite Nanoparticles. Journal of the American Chemical Society. 2002;124(28):8204-5.
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[19] Radu T, Iacovita C, Benea D, Turcu R. X-Ray Photoelectron Spectroscopic Characterization of Iron Oxide Nanoparticles. Applied Surface Science. 2017;405:337-43.
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[20] Cornell RM, Schwertmann U. The iron oxides: structure, properties, reactions, occurrences and uses: John Wiley & Sons; 2003.
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[21] Krehula S, Musić S. The influence of Cd-dopant on the properties of α-FeOOH and α-Fe2O3 particles precipitated in highly alkaline media. Journal of Alloys and Compounds. 2007;431(1-2):56-64.
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[22] Schwaminger SP, García PF, Merck GK, Bodensteiner FA, Heissler S, Günther S, et al. Nature of Interactions of Amino Acids with Bare Magnetite Nanoparticles. The Journal of Physical Chemistry C. 2015;119(40):23032-41.
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[23] Yu BY, Kwak S-Y. Assembly of magnetite nanocrystals into spherical mesoporous aggregates with a 3-D wormhole-like pore structure. Journal of Materials Chemistry. 2010;20(38):8320.
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[24] Zhao H, Chen Z, Tao L, Zhu X, Lan M, Li Z. In vitro toxicity evaluation of ultra-small MFe2O4 (M = Fe, Mn, Co) nanoparticles using A549 cells. RSC Advances. 2015;5(84):68454-60.
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[25] Lai Y, Yin W, Liu J, Xi R, Zhan J. One-Pot Green Synthesis and Bioapplication of l-Arginine-Capped Superparamagnetic Fe3O4 Nanoparticles. Nanoscale Research Letters. 2009;5(2):302-7.
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[26] Pavelec J, Hulva J, Halwidl D, Bliem R, Gamba O, Jakub Z, et al. A multi-technique study of CO2 adsorption on Fe3O4 magnetite. The Journal of Chemical Physics. 2017;146(1):014701.
26
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27
[28] Ataman E, Isvoranu C, Knudsen J, Schulte K, Andersen JN, Schnadt J. Adsorption of L-cysteine on rutile TiO2(110). Surface Science. 2011;605(1-2):179-86.
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[30] Kaiser R, Miskolczy G. Magnetic Properties of Stable Dispersions of Subdomain Magnetite Particles. Journal of Applied Physics. 1970;41(3):1064-72.
30
[31] Safronov AP, Beketov IV, Komogortsev SV, Kurlyandskaya GV, Medvedev AI, Leiman DV, et al. Spherical magnetic nanoparticles fabricated by laser target evaporation. AIP Advances. 2013;3(5):052135.
31
ORIGINAL_ARTICLE
Efficient Suzuki and Sonogashira coupling reactions catalyzed by Pd/DNA@MWCNTs in green solvents and under mild conditions
The palladium nanoparticles were immobilized on DNA-modified multi walled carbon nanotubes as stable and powerful heterogeneous catalyst. The catalyst was characterized by FT-IR spectroscopy, UV-Vis spectroscopy, field emission scanning electron microscopy, X-ray diffraction, transmission electron microscopy, inductively coupled plasma and elemental analysis. DNA as a well-defined structure and biodegradable natural polymer was used to make the palladium catalyst which shows a high activity in Suzuki and Sonogashira cross-coupling reactions in excellent yields and good selectivity under ligand-free and mild reaction conditions. Moreover, the catalyst could be recovered and reused several times without any considerable loss of its catalytic activity. This air- and moisture-stable phosphine-free palladium catalyst was found to be highly active in aqueous ethanol with extremely small amount of palladium under mild conditions. To the best of our knowledge, this is the first report on using DNA base heterogonous catalyst for Suzuki and Sonogashira cross-coupling reactions.
http://www.nanochemres.org/article_97017_ce6800e21e02b98afdf3442c737224fb.pdf
2019-10-01
132
139
10.22036/ncr.2019.02.004
Suzuki
Sonogashira
DNA
Multi Walled Carbon Nanotubes
Heterogeneous catalyst
Abdol R.
Hajipour
neda_iut_83@yahoo.com
1
Department of Chemistry, Isfahan University of Technology, Isfahan, Iran
LEAD_AUTHOR
Zahra
Khorsandi
khorsandiz_91@yahoo.com
2
Department of Chemistry, Isfahan University of Technology, Isfahan, Iran
LEAD_AUTHOR
1. Zarei A, Khazdooz L, Hajipour AR, Rafiee F, Azizi G, Abrishami F. Suzuki–Miyaura cross-coupling of aryldiazonium silica sulfates under mild and heterogeneous conditions. Tetrahedron Letters. 2012;53(4):406-8.
1
2. Aghahosseini H, Tabatabaei Rezaei SJ, Maleki M, Abdolahnjadian D, Ramazani A, Shahroosvand H. Pt(II)-Based Artificial Nitroreductase: An Efficient and Highly Stable Nanozyme. ChemistrySelect. 2019;4(4):1387-93.
2
3. Kalantari F, Ramazani A, Heravi MRP. Recent Advances in the Applications of Hybrid Magnetic Nanomaterials as Magnetically Retrievable Nanocatalysts. Current Organic Chemistry. 2019;23(2):136-63.
3
4. Yaghoubi A, Ramazani A. Synthesis of Amino-functionalized Carbon Nanotubes and their Applications. Current Organic Chemistry. 2018;22(15):1505-22.
4
5. Aghahosseini H, Tabatabaei Rezaei SJ, Tadayyon M, Ramazani A, Amani V, Ahmadi R, et al. Highly Efficient Aqueous Synthesis of Propargylamines through C–H Activation Catalyzed by Magnetic Organosilica-Supported Gold Nanoparticles as an Artificial Metalloenzyme. European Journal of Inorganic Chemistry. 2018;2018(22):2589-98.
5
6. Motevalizadeh SF, Alipour M, Ashori F, Samzadeh-Kermani A, Hamadi H, Ganjali MR, et al. Heck and oxidative boron Heck reactions employing Pd(II) supported amphiphilized polyethyleneimine-functionalized MCM-41 (MCM-41@aPEI-Pd) as an efficient and recyclable nanocatalyst. Applied Organometallic Chemistry. 2018;32(3):e4123.
6
7. Ramazani A, Khoobi M, Sadri F, Tarasi R, Shafiee A, Aghahosseini H, et al. Efficient and selective oxidation of alcohols in water employing palladium supported nanomagnetic Fe3O4@hyperbranched polyethylenimine (Fe3O4@HPEI.Pd) as a new organic–inorganic hybrid nanocatalyst. Applied Organometallic Chemistry. 2018;32(1):e3908.
7
8. Hajipour AR, Boostani E, Mohammadsaleh F. Proline-functionalized chitosan–palladium(ii) complex, a novel nanocatalyst for C–C bond formation in water. RSC Advances. 2015;5(31):24742-8.
8
9. Hajipour AR, Khorsandi Z. Immobilized Pd on (S)-methyl histidinate-modified multi-walled carbon nanotubes: a powerful and recyclable catalyst for Mizoroki–Heck and Suzuki–Miyaura C–C cross-coupling reactions in green solvents and under mild conditions. Applied Organometallic Chemistry. 2016;30(5):256-61.
9
10. Hajipour AR, Tadayoni NS, Khorsandi Z. Magnetic iron oxide nanoparticles–N-heterocyclic carbene–palladium(II): a new, efficient and robust recyclable catalyst for Mizoroki–Heck and Suzuki–Miyaura coupling reactions. Applied Organometallic Chemistry. 2016;30(7):590-5.
10
11. Hajipour AR, Rafiee F. Synthesis of substituted biaryls via Suzuki, Stille and Hiyama cross-coupling and homo-coupling reactions by CN-dimeric and monomeric ortho-palladated catalysts. Applied Organometallic Chemistry. 2013;27(7):412-8.
11
12. Paul S, Clark JH. A highly active and reusable heterogeneous catalyst for the Suzuki reaction: synthesis of biaryls and polyaryls. Green Chemistry. 2003;5(5):635-8.
12
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60
ORIGINAL_ARTICLE
Eco-friendly synthesis and characterization of α-Fe2O3 nanoparticles and study of their photocatalytic activity for degradation of Congo red dye
In this work, α-Fe2O3 (hematite) nanoparticles were synthesized using Arabic gum (AG) as a biotemplate source by the sol-gel method. This method has many advantages such as low-cost, nontoxicity, simple work-up, high efficiency, compounds uniformity, and high efficiency. The α-Fe2O3 nanoparticles were characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), UV-visible diffuse reflectance spectroscopy (DRS), field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). The results of XRD analysis revealed the formation of the rhombohedral phase of α-Fe2O3 nanoparticles with an average crystallite size of 19 nm. The TEM image illustrated the α-Fe2O3 nanoparticles with average particle size of 45-50 nm. The application of α-Fe2O3 nanoparticles as a photocatalyst was investigated for the degradation of the Congo red dye. The effects of photocatalyst dosage, initial dye concentration and visible light irradiation on dye degradation were assessed. The results demonstrated that the catalyst could degrade90% of the Congo red dye in 90 min. The α-Fe2O3 nanoparticles exhibited slight decrease in photocatalytic degradation of Congo red dye after four recycles.
http://www.nanochemres.org/article_96971_d22e54b611c11121962128cf6e77e154.pdf
2019-10-01
140
147
10.22036/ncr.2019.02.005
α-Fe2O3 nanoparticles
Green synthesis
Arabic gum
dye degradation
Saeid
Taghavi Fardood
saeidt64@gmail.com
1
Department of Chemistry, University of Zanjan, Zanjan, Iran
LEAD_AUTHOR
Ferzaneh
Moradnia
farzaneh2856@gmail.com
2
Department of Chemistry, University of Zanjan, Zanjan, Iran
AUTHOR
Sajjad
Moradi
sajad.moradi.ir@gmail.com
3
Department of Chemistry, University of Zanjan, Zanjan, Iran
AUTHOR
Reza
Forootan
forootanreza23@gmail.com
4
Department of Chemistry, University of Zanjan, Zanjan, Iran
AUTHOR
Fateme
Yekke Zare
f.zare529@gmail.com
5
Department of Chemistry, University of Zanjan, Zanjan, Iran
AUTHOR
Maryam
Heidari
chemist_1364@yahoo.com
6
Department of Chemistry, University of Zanjan, Zanjan, Iran
AUTHOR
1. Cañas-Carrell J, Li S, Parra A, Shrestha B. Metal oxide nanomaterials: health and environmental effects. Health and Environmental Safety of Nanomaterials: Elsevier; 2014. p. 200-21.
1
2. Saeidian H, Moradnia F. Benign synthesis of N-aryl-3,10-dihydroacridin-1(2H)-one derivatives via ZnO nanoparticle-catalyzed Knoevenagel condensation/intramolecular enamination reaction. Iranian Chemical Communication. 2017;5(Issue 3, pp. 237-363):252-61.
2
3. Ramazani A, Moradnia F, Aghahosseini H, Abdolmaleki I. Several Species of Nucleophiles in the Smiles Rearrangement. Current Organic Chemistry. 2017;21(16):1612-25.
3
4. Taghavi Fardood S, Ramazani A. Black Tea Extract Mediated Green Synthesis of Copper Oxide Nanoparticles. Journal of Applied Chemical Research. 2018; 12(2): 8-15.
4
5. Ramazani A, Farshadi A, Mahyari A, Sadri F, Joo SW, Asiabi PA, et al. Synthesis of electron-poor N-Vinylimidazole derivatives catalyzed by Silica nanoparticles under solvent-free conditions. International Journal of Nano Dimension. 2016; 7(1): 41.
5
6. Sadri F, Ramazani A, Ahankar H, Taghavi Fardood S, Azimzadeh Asiabi P, Khoobi M, et al. Aqueous-phase oxidation of alcohols with green oxidants (oxone and hydrogen peroxide) in the presence of MgFe2O4 magnetic nanoparticles as an efficient and reusable catalyst. Journal of Nanostructures. 2016; 6(4): 264-72.
6
7. Saeidian H, Mirjafary Z, Abdolmaleki E, Moradnia F. An Expedient Process for the Synthesis of 2-(N-Arylamino)benzaldehydes from 2-Hydroxybenzaldehydes via Smiles Rearrangement. Synlett. 2013;24(16):2127-31.
7
8. Khayyat SA, Akhtar M, Umar A. ZnO nanocapsules for photocatalytic degradation of thionine. Materials Letters. 2012;81:239-41.
8
9. Rekavandi N, Malekzadeh A, Ghiasi E. Methyl orange degradation over nano-LaMnO3 as a green catalyst under the mild conditions. Nanochemistry Research. 2019; 4(1): 1-10.
9
10. Houshmand R, Banna Motejadded Emrooz H. Photocatalytic outcomes for methylene blue degradation from CTAB mediated mesoporous ZnS, synthesized with an insoluble precursor in ethanol media. Nanochemistry Research. 2019; 4(1): 64-76.
10
11. Singh R, Kumar M, Tashi L, Khajuria H, Sheikh HN. Hydrothermal synthesis of nitrogen doped graphene supported cobalt ferrite (NG@ CoFe2O4) as photocatalyst for the methylene blue dye degradation. Nanochemistry Research. 2018;3(2):149-59.
11
12. Zhou H, Wong SS. A facile and mild synthesis of 1-D ZnO, CuO, and α-Fe2O3 nanostructures and nanostructured arrays. Acs Nano. 2008;2(5):944-58.
12
13. Taghavi Fardood S, Ramazani A, Golfar Z, Joo SW. Green Synthesis of α-Fe2O3 (hematite) Nanoparticles using Tragacanth Gel. Journal of Applied Chemical Research. 2017; 11(3): 19-27.
13
14. Valenzuela M, Bosch P, Jiménez-Becerrill J, Quiroz O, Páez A. Preparation, characterization and photocatalytic activity of ZnO, Fe2O3 and ZnFe2O4. Journal of Photochemistry and photobiology A: Chemistry. 2002;148(1-3):177-82.
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15. Kennedy JH, Frese KW. Photooxidation of water at α‐Fe2O3 electrodes. Journal of the Electrochemical Society. 1978;125(5):709-14.
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16. Lindgren T, Wang H, Beermann N, Vayssieres L, Hagfeldt A, Lindquist S-E. Aqueous photoelectrochemistry of hematite nanorod array. Solar Energy Materials and Solar Cells. 2002;71(2):231-43.
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17. Chen J, Xu L, Li W, Gou X. α‐Fe2O3 nanotubes in gas sensor and lithium‐ion battery applications. Advanced Materials. 2005;17(5):582-6.
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18. Gondal MA, Hameed A, Yamani Z, Suwaiyan A. Laser induced photo-catalytic oxidation/splitting of water over α-Fe2O3, WO3, TiO2 and NiO catalysts: activity comparison. Chemical Physics Letters. 2004;385(1-2):111-5.
18
19. Ohmori T, Takahashi H, Mametsuka H, Suzuki E. Photocatalytic oxygen evolution on α-Fe2O3 films using Fe3+ ion as a sacrificial oxidizing agent. Physical Chemistry Chemical Physics. 2000;2(15):3519-22.
19
20. Suber L, Fiorani D, Imperatori P, Foglia S, Montone A, Zysler R. Effects of thermal treatments on structural and magnetic properties of acicular α-Fe2O3 nanoparticles. NanoStructured Materials. 1999;11(6):797-803.
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21. Reddy CG, Seela KK, Manorama S. Preparation of γ-Fe2O3 by the hydrazine method: Application as an alcohol sensor. International Journal of Inorganic Materials. 2000; 2(4): 301-7.
21
22. Jing Z, Wu S, Zhang S, Huang W. Hydrothermal fabrication of various morphological α-Fe2O3 nanoparticles modified by surfactants. Materials research bulletin. 2004;39(13):2057-64.
22
23. Moradnia F, Ramazani A, Taghavi Fardood S, Gouranlou F. A novel green synthesis and characterization of tetragonal-spinel MgMn2O4 nanoparticles by tragacanth gel and studies of its photocatalytic activity for degradation of reactive blue 21 dye under visible light. Materials Research Express. 2019;6(7):075057.
23
24. Habibi MH. Synthesis, characterization and photocatalytic properties of Iron oxide nanoparticles synthesized by sol-gel autocombustion with ultrasonic irradiation. Nanochemistry Research. 2017; 2(2): 166-71.
24
25. Atrak K, Ramazani A, Taghavi Fardood S. A novel sol–gel synthesis and characterization of MgFe2O4@ γ–Al2O3 magnetic nanoparticles using tragacanth gel and its application as a magnetically separable photocatalyst for degradation of organic dyes under visible light. Journal of Materials Science: Materials in Electronics. 2018;29(8):6702-10.
25
26. Taghavi Fardood S, Moradnia F, Mostafaei M, Afshari Z, Faramarzi V, Ganjkhanlu S. Biosynthesis of MgFe2O4 magnetic nanoparticles and its application in photo-degradation of malachite green dye and kinetic study. Nanochemistry Research. 2019; 4(1): 86-93.
26
27. Taghavi Fardood S, Ramazani A, Moradnia F, Afshari Z, Ganjkhanlu S, Yekke Zare F. Green Synthesis of ZnO Nanoparticles via Sol-gel Method and Investigation of Its Application in Solvent-free Synthesis of 12-Aryl-tetrahydrobenzo[α]xanthene-11-one Derivatives Under Microwave Irradiation. Chemical Methodologies. 2019; 3(Issue 6. pp. 684-795): 696-706.
27
28. Atrak K, Ramazani A, Taghavi Fardood S. Eco-friendly synthesis of Mg0.5Ni0.5AlxFe2-xO4 magnetic nanoparticles and study of their photocatalytic activity for degradation of direct blue 129 dye. Journal of Photochemistry and Photobiology A: Chemistry. 2019;382:111942.
28
29. Ouni L, Ramazani A, Taghavi Fardood S. An overview of carbon nanotubes role in heavy metals removal from wastewater. Frontiers of Chemical Science and Engineering. 2019;13(2):274–95.
29
30. Moradi S, Taghavi Fardood S, Ramazani A. Green synthesis and characterization of magnetic NiFe2O4@ZnO nanocomposite and its application for photocatalytic degradation of organic dyes. Journal of Materials Science: Materials in Electronics. 2018;29(16):14151-60.
30
31. Amini M, Ashrafi M. Photocatalytic degradation of some organic dyes under solar light irradiation using TiO2 and ZnO nanoparticles. Nanochemistry Research. 2016; 1(1): 79-86.
31
32. Taghavi Fardood S, Moradnia F, Ramazani A. Green synthesis and characterisation of ZnMn2O4 nanoparticles for photocatalytic degradation of Congo red dye and kinetic study. Micro & Nano Letters. 2019;14(9):986-91.
32
33. Zhao B, Wang Y, Guo H, Wang J, He Y, Jiao Z, et al. Iron oxide(III) nanoparticles fabricated by electron beam irradiation method. Materials Science Poland. 2007; 25(4): 1143-8.
33
34. Taghavi Fardood S, Ramazani A, Joo SW. Eco-friendly synthesis of magnesium oxide nanoparticles using arabic Gum. Journal of Applied Chemical Research. 2018; 12(1): 8-15.
34
35. Nouri J, Khoshravesh T, Khanahmadzadeh S, Salehabadi A, Enhessari M. Synthesis, characterization and optical band gap of Lithium cathode materials: Li2Ni8O10 and LiMn2O4 nanoparticles. International Journal of Nano Dimension. 2016; 7(1): 15-24.
35
ORIGINAL_ARTICLE
Synthesis of CuO nanorods via thermal decomposition of copper-dipicolinic acid complex
Template-free CuO nanorods were synthesized through a three-step chemical method with no water-insoluble materials. The first step included the preparation of a Cu-complex, which was obtained from dipicolinic acid, L-lysine, and copper nitrate. Then, as the second step, the obtained solution was allowed to be relaxed for a week to and formation of some blue single-crystals single crystals, which would be assigned as a square-pyramidal copper complex by according to study analyzing its single-crystal single crystal structure. Finally, as the third step, the blue prepared Cu-complex should be calcined to synthesis the CuO phase. Simultaneous thermal analysis (STA) was utilized to determine the optimum calcination temperature. Its results and showed that 600 ºC is the optimum temperature. X-ray diffraction (XRD) analysis approved the formation of the CuO phase without any impurity which is matched with the monoclinic CuO standard lines (PDF No.: 74-1021). Especially, the as-prepared CuO powder has shown clear nanorod morphology in transmission electron microscopy (TEM) images and exhibit a notable optical behavior and high band gap bandgap energy (Eg = 2.8 eV) in comparison to that of bulk CuO (Eg = 1.9-2 eV).
http://www.nanochemres.org/article_104934_a75ba2427f9f343cf018663d55567c02.pdf
2019-10-01
148
153
10.22036/ncr.2019.02.006
CuO nanorod
template-free synthesis
copper-dipicolinic acid complex
decomposition of a Cu-complex
TEM
Mehrnaz
Gharagozlou
gharagozlou@icrc.ac.ir
1
Department of Nanomaterials and Nanocoatings, Institute for Color Science and Technology, Tehran, Iran.
LEAD_AUTHOR
Sanaz
Naghibi
naghibi@iaush.ac.ir
2
Department of Materials Engineering, Shahreza Branch, Islamic Azad University, Shahreza, Iran.
AUTHOR
1. Dubal DP, Gund GS, Lokhande CD, Holze R. CuO cauliflowers for supercapacitor application: Novel potentiodynamic deposition. Materials Research Bulletin. 2013;48(2):923-8.
1
2. Kim S-I, Hwang J-H, Lim TY, Kim J-H, Kim YH, Lee J-H, et al. Effect of CuO on the Optical and Structural Properties of Phosphate Glass for Near-Infrard Filter2009. 657-60 p.
2
3. Wang F, Li H, Yuan Z, Sun Y, Chang F, Deng H, et al. A highly sensitive gas sensor based on CuO nanoparticles synthetized via a sol–gel method. RSC Advances. 2016;6(83):79343-9.
3
4. da S. Dias C, de M. Lima T, Lima CGS, Zuekrman-Schpector J, Schwab RS. CuO Nanoparticles as An Efficient Heterogeneous Catalyst for the 1,3-Dipolar Cycloaddition of Dicarbonyl Compounds to Azides. ChemistrySelect. 2018;3(22):6195-202.
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5. Xiao G, Gao P, Wang L, Chen Y, Wang Y, Zhang G. Ultrasonochemical-Assisted Synthesis of CuO Nanorods with High Hydrogen Storage Ability. Journal of Nanomaterials. 2011;2011:6.
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6. Zeng Q-X, Xu G-C, Zhang L, Lin H, Lv Y, Jia D-Z. Porous CuO nanofibers derived from a Cu-based coordination polymer as a photocatalyst for the degradation of rhodamine B. New Journal of Chemistry. 2018;42(9):7016-24.
6
7. Li D, Zu X, Ao D, Tang Q, Fu Y, Guo Y, et al. High humidity enhanced surface acoustic wave (SAW) H2S sensors based on sol–gel CuO films. Sensors and Actuators B: Chemical. 2019;294:55-61.
7
8. Tiwari PK, Shweta, Singh AK, Singh VP, Prasad SM, Ramawat N, et al. Liquid assisted pulsed laser ablation synthesized copper oxide nanoparticles (CuO-NPs) and their differential impact on rice seedlings. Ecotoxicology and Environmental Safety. 2019;176:321-9.
8
9. Lugo-Ruelas M, Amézaga-Madrid P, Esquivel-Pereyra O, Antúnez-Flores W, Pizá-Ruiz P, Ornelas-Gutiérrez C, et al. Synthesis, microstructural characterization and optical properties of CuO nanorods and nanowires obtained by aerosol assisted CVD. Journal of Alloys and Compounds. 2015;643:S46-S50.
9
10. Yuan B, Liu X, Liu J, Li M, Wang D. Synthesis of different morphologies CuO nanocrystalline under room temperature. Materials Letters. 2019;236:495-7.
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11. Kumar K, Priya A, Arun A, Hait S, Chowdhury A. Antibacterial and natural room-light driven photocatalytic activities of CuO nanorods. Materials Chemistry and Physics. 2019;226:106-12.
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12. Ayesh AI, Ahmed RE, Al-Rashid MA, Alarrouqi RA, Saleh B, Abdulrehman T, et al. Selective gas sensors using graphene and CuO nanorods. Sensors and Actuators A: Physical. 2018;283:107-12.
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13. Arockiasamy JSK, Irudayaraj J. Natural dye sensitized CuO nanorods for luminescence applications. Ceramics International. 2016;42(5):6198-205.
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15. Chahrour KM, Ahmed NM, Hashim MR, Elfadill NG, Bououdina M. Self-assembly of aligned CuO nanorod arrays using nanoporous anodic alumina template by electrodeposition on Si substrate for IR photodetectors. Sensors and Actuators A: Physical. 2016;239:209-19.
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16. Nishtar N, Fathima N, Rajaram A, Bojja S, Mandal A. The formation of copper oxide nanorods in the presence of various surfactant micelles. Indian Journal of Science and Technology. 2008;1(7): 1-6.
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17. Cheng G. Synthesis and characterisation of CuO nanorods via a hydrothermal method. Micro & Nano Letters. 2011;6(9):774-6.
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18. Kumar K, Chowdhury A. Facile synthesis of CuO nanorods obtained without any template and/or surfactant. Ceramics International. 2017;43(16):13943-7.
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19. Gopalakrishnan M, Kingson Solomon Jeevaraj A. Template-free solvothermal synthesis of copper oxide nanorods. Materials Science in Semiconductor Processing. 2014;26:512-5.
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20. Li XM, Li SS, Ma X, Tang K, Wang Z, Hao X, et al. Template-free electro-synthesis of PbO2 nanorod with chrysanthemum-like array. Materials Letters. 2019;238:85-8.
20
21. Gharagozlou M, Naghibi S, Ataei M. Water-based synthesis of ZnO nanoparticles via decomposition of a ternary zinc complex containing Schiff-base, chelating, and Phen ligands. Journal of the Chinese Chemical Society. 2018;65(10):1210-7.
21
22. Gharagozlou M, Naghibi S. Synthesis of ZnO Nanoparticles Based on Zn Complex Achieved from L-leucine. Journal of the Chinese Chemical Society. 2016;63(3):290-7.
22
23. Gao X, He S, Zhang C, Du C, Chen X, Xing W, et al. Single Crystal Sub-Nanometer Sized Cu(6)(SR)(6) Clusters: Structure, Photophysical Properties, and Electrochemical Sensing. Adv Sci (Weinh). 2016;3(12):1600126-.
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24
25. Chen H, Zhao G, Liu Y. Low-temperature solution synthesis of CuO nanorods with thin diameter. Materials Letters. 2013;93:60–3.
25
ORIGINAL_ARTICLE
Co3O4/NiO@GQDs@SO3H nanocomposite as an effective catalyst for the synthesis of pyranopyridines
Co3O4/NiO@GQDs@SO3H nanocatalyst has been used as an effective catalyst for the preparation of benzopyranopyridines through a four-component reaction of salicylaldehydes, thiols and 2 equiv of malononitrile under reflux condition in ethanol. The catalyst has been characterized by FT-IR, XRD, SEM, EDS, BET, XPS, TGA and VSM. Atom economy, reusable catalyst, low catalyst loading, applicability to a wide range of substrates and high yields of products are some of the notable features of this method. The best results were gained in EtOH and we found that the reaction gave convincing results in the presence of Co3O4/NiO@GQDs@SO3H nanocomposite (4 mg) under reflux conditions. A series of salicylaldehydes and different thiols were studied under optimum conditions.We also determined recycling of Co3O4/NiO@GQDs@SO3H nanocomposite as catalyst for the model reaction under reflux conditions in ethanol. The results showed that nanocomposite can be reused several times without noticeable loss of catalytic activity (Yields 90 to 88%)
http://www.nanochemres.org/article_104935_2c3f980cb67e3c3684a7227ff4466897.pdf
2019-10-01
154
162
10.22036/ncr.2019.02.007
Nanocomposite
One-pot
Heterogeneous catalysts
pyranopyridines
nanoanalysis
Hossein
Shahbazi-Alavi
hossien_shahbazi@yahoo.com
1
Young Researchers and Elite Club, Kashan Branch, Islamic Azad University, Kashan, Iran
LEAD_AUTHOR
Ali
Kareem Abbas
kareemabbasali@yahoo.com
2
College of applied medical sciences, University of kerbala, Iraq
AUTHOR
Javad
Safaei-Ghomi
safaeikashanu@yahoo.com
3
Department of Organic Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
AUTHOR
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35
ORIGINAL_ARTICLE
Plant extract mediated biosynthesis of Al2O3 nanoparticles- a review on plant parts involved, characterization and applications
Metal oxide nanoparticles (NPs) produced by green chemistry approaches have received notable attention because of their significant physic-chemical properties and their remarkable uses in the area of nanotechnology. Currently, the sustainable improvement of synthesizing NPs by distinctive parts of plant extract has become a major focus of scientists and researchers because of these NPs have minimum pernicious effect in the ecosystem and minimum noxiousness for the human health. Among the all metal oxide nanoparticles, alumina nanoparticles (Al2O3 NPs) draw peculiar attention due to their significant applications in ceramics, textiles, drug delivery, catalysis, waste-water treatment and biosensor. Many natural biomolecules in plant extracts such as saponins, tannins, alkaloids, amino acids, enzymes, proteins, coumarins, polysaccharides, polyphenols, steroid and vitamins could be participated in bioreduction and stabilization of Al2O3 NPs. In the last decade, innumerable efforts were made to develop a sustainable eco-accommodating method of synthesis to avoid the perilous byproducts. In this review, I focused on the plants which are used for the green fabrication of Al2O3 NPs, their characterization methods and applications are investigated.
http://www.nanochemres.org/article_104936_a654baaa15b04cf11133e3de67dded61.pdf
2019-10-01
163
169
10.22036/ncr.2019.02.008
Nanotechnology
Green synthesis
Plant extracts
Al2O3 NPs
applications
Suresh
Ghotekar
ghotekarsuresh7@gmail.com
1
Department of Chemistry, Sanjivani Arts, Commerce and Science College, Kopargaon 423 603, Savitribai Phule Pune University, Maharashtra, India
LEAD_AUTHOR
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1
2. Ghotekar S. A review on plant extract mediated biogenic synthesis of CdO nanoparticles and their recent applications. Asian Journal of Green Chemistry. 2019;3(2):187-200.
2
3. Sorbiun M, Shayegan Mehr E, Ramazani A, Mashhadi Malekzadeh A. Biosynthesis of metallic nanoparticles using plant extracts and evaluation of their antibacterial properties. Nanochemistry Research. 2018;3(1):1-16.
3
4. Nikam A, Pagar T, Ghotekar S, Pagar K, Pansambal S. A review on plant extract mediated green synthesis of zirconia nanoparticles and their miscellaneous applications. Journal of Chemical Reviews. 2019;1(3. pp. 154-251):154-63.
4
5. Pansambal S, Deshmukh K, Savale A, Ghotekar S, Pardeshi O, Jain G, et al. Phytosynthesis and biological activities of fluorescent CuO nanoparticles using Acanthospermum hispidum L. extract. Journal of Nanostructures. 2017;7(3):165-74.
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8
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13
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16. Pagar K, Ghotekar S, Pagar T, Nikam A, Pansambal S, Oza R, et al. Antifungal activity of biosynthesized CuO nanoparticles using leaves extract of Moringa oleifera and their structural characterizations. Asian Journal of Nanosciences and Materials. 2020;3(1):15-23.
16
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ORIGINAL_ARTICLE
Efficiency of Cu, Ag, and Fe Nanoparticles As Detergents Preservatives Against E. coli and S. aureus
In this study, Cu, Ag, and Fe nanoparticles (NPs) are used in shampoo, hand washing liquid (HWL) and dish washing liquid (DWL) instead of the conventional synthetic preservatives such as isothiazolinones; since the latter often act as potent sensitizers that leads to development of allergic contact dermatitis. The above NPs are considerably effective against Escherichia coli and Staphylococcus aureus. Our metal NPs are deliberately made durable and pure through arc fabrication. They appear in spherical morphology as indicated by XRD and SEM. This study clearly demonstrates the advantages of using rather low concentrations of Ag, Cu and Fe NPs as preservatives instead of carcinogenic Kathone CG, which is commonly used in detergent products.The shampoo formulation with 0.1 g/L Cu NPs and HWL and DWL with 0.1 g/L Ag NPs exhibit the best antibacterial activity against tested E. coli and S. aureus. Generally, the order of antibacterial activity of these preservatives is: Cu NPs>Ag NPs> Fe NPs.
http://www.nanochemres.org/article_104937_b60a25adb3bc9cad3d7ef287d115242a.pdf
2020-03-16
170
178
10.22036/ncr.2019.02.009
Silver
Iron
copper
Detergent
preservative
Marzieh
Miranzadeh
marzieh.miranzadeh@gmail.com
1
Department of Chemistry, Tarbiat Modares University, Tehran, Iran
AUTHOR
Mohammad
Kassaee
kassaeem@modares.ac.ir
2
Department of Chemistry, Tarbiat Modares University, Tehran, Iran
LEAD_AUTHOR
Fahimeh
Afshari
afshari.rsi@gmail.com
3
Industrial paints of Iran Co., Isfahan, Iran
AUTHOR
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