%0 Journal Article %T A new approach for the synthesis of 3,4-dihydropyrano[c]chromenes and biscoumarins using {[2,2’-BPyH][C(CN)3]2} as a bifunctional nanostructured ionic liquid catalyst %J Nanochemistry Research %I Iranian Chemical Society %Z 2538-4279 %A Mansouri, Navid %A Baghery, Saeed %A Zolfigol, Mohammad Ali %D 2018 %\ 12/01/2018 %V 3 %N 2 %P 170-177 %! A new approach for the synthesis of 3,4-dihydropyrano[c]chromenes and biscoumarins using {[2,2’-BPyH][C(CN)3]2} as a bifunctional nanostructured ionic liquid catalyst %K 3 %K 4-Dihydropyrano[c]chromene %K Biscoumarin %K Ionic Liquid %K Solvent-free condition %R 10.22036/ncr.2018.02.006 %X [2,2'-Bipyridine]-1,1'-diium tricyanomethanide {[2,2'-BPyH][C(CN)3]2} as a bifunctional nanostructured ionic liquid catalyst (0.5 mol%) was used for the synthesis of 3,4-dihydropyrano[c]chromenes (14 examples) under solvent-free condition at room temperature in high yield (82-91%) and short reaction time. In addition, the described ionic liquid catalyst was also applied for the synthesis of biscoumarins (8 examples) under the same reaction condition in good yield (87-91%) and short reaction time. The {[2,2'-BPyH][C(CN)3]2} was attained by the reaction of 2,2'-Bipyridine (5 mmol) and 5 mL an aqueous solution of tricyanomethane (5 mmol) at room temperature for 3 hours. The {[2,2'-BPyH][C(CN)3]2} was obtained with high purity that was approved by FTIR, 1H NMR, 13C NMR, mass, TG, DTA, XRD, SEM, TEM analysis and melting-point determination. The catalyst was recovered in excellent yield and was used in the revealed reaction 5 times without the need of additional catalyst. The major advantages of the presented procedure are efficient catalysis and good cost efficiency. %U http://www.nanochemres.org/article_81107_59c8167b715c5778a16623f07db59e38.pdf